Pericàs
Research group
Abstract
Over the last years, the Pericàs laboratory at ICIQ has been engaged in a broad research program aimed at developing a complete toolkit of polymer-supported and magnetic nanoparticle-immobilized catalysts with optimized characteristics of catalytic activity, high induced stereoselectivity and extended life cycle.
The ultimate goal of this research has been the development of single-pass, catalytic and enantioselective flow versions of the most relevant processes for organic synthesis, contributing in this manner to a more sustainable practice of chemical synthesis. Our laboratory at ICIQ has been pioneer in this effort, being recognized as one of the leaders in the field.
Topics addressed
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- Supported organocatalysts and flow processes
- Visible light-mediated catalytic processes
- Enantioselective homogeneous organo-catalysis
- Metal-mediated catalysis
Articles
“Visible-Light-Promoted Arylation Reactions Photocatalyzed by Bismuth(III) Oxide”
L. Buglioni, P. Riente, E. Palomares, M.A. Pericàs
Eur. J. Org. Chem. 2017, 6986-6990.
“Polystyrene-supported bifunctional resorcinarenes as cheap, metal-free and recyclable catalysts for epoxide/CO2 coupling reactions”
T. Jose, S. Cañellas, M.A. Pericàs, A.W. Kleij
Green Chem. 2017,19, 5488-5493.
“5,5′-Bistriazoles as axially chiral, multidentate ligands: synthesis, configurational stability and catalytic application of their scandium(III) complexes”
P. Etayo, E.C. Escudero-Adán, M.A. Pericàs
Catal. Sci. Technol. 2017, 4830-4841.
“Catalytic Asymmetric [8+2] Annulation Reactions Promoted by a Recyclable Immobilized Isothiourea”
S. Wang, C. Rodríguez-Escrich, M.A. Pericàs
Angew. Chem. Int. Ed. 2017, 15068-15072.
“Asymmetric Visible-Light Photoredox Cross-Dehydrogenative Coupling of Aldehydes with Xanthenes”
E. Larionov, M.M. Mastandrea, M.A. Pericàs
ACS Catal. 2017,7008-7013.
“Modular Synthesis of Triazole-based Chiral Iodoarenes for Enantioselective Spirocyclizations”
C. Hempel, C. Maichle-Moessmer, M.A. Pericàs, B.J. Nachtsheim
Adv. Synth. Catal. 2017, 2931-2941.
“cis-4-Alkoxydialkyl- and cis-4-Alkoxydiarylprolinol Organocatalysts: High Throughput Experimentation (HTE)-Based and Design of Experiments (DoE)-Guided Development of a Highly Enantioselective aza-Michael Addition of Cyclic Imides to α,β-Unsaturated Aldehydes”
I. Arenas, A. Ferrali, C. Rodriguez-Escrich, F. Bravo, M.A. Pericàs
Adv. Synth. Catal. 2017, 2414-2424.
“Asymmetric [4 + 2] Annulation Reactions Catalyzed by a Robust, Immobilized Isothiourea”
S. Wang, J. Izquierdo, C. Rodríguez-Escrich, M.A. Pericàs
ACS Catal. 2017, 7, 2780-2785.
“A Highly Active Polymer-Supported Catalyst for Asymmetric Robinson Annulations in Continuous Flow”
S. Cañellas, C. Ayats, A. H. Henseler, M. A. Pericàs.
ACS Catal. 2017, 7 (2), 1383-1391.